An Analysis of Observations from Portable Temperature and Humidity Sensors Deployed Across Oklahoma City

This study focused on the variability of temperature across the Oklahoma City metropolitan area (OKC) during a six-week period in early 2007. Twenty portable temperature and humidity sensors were strategically placed at various fire stations throughout Oklahoma City from 20 February through 1 April 2007. Data from these sensors and two local Oklahoma Mesonet sites were used to evaluate the spatial differences in temperature for the area.

Schreinemakers Rule as Applied to Non-Degenerate Ternary Systems

In experimental studies of phase relations in chemical, ceramic, metallurgical, and mineralogical systems, it is fairly rare for pressure-temperature (P-T) diagrams to be fully mapped, i.e. with all the univariant lines directly determined. This typically requires an extraordinarily large number of experiments; in many cases this is impractical or, due to extreme temperature or pressure conditions, sluggish kinetics, or other considerations, effectively impossible. Even if the availability of thermodynamic data allows the slopes of such univariant curves to be calculated, there remains a possibility that such data are not always mutually consistent. Fortunately, in a series of classic monographs published in Dutch between 1915 and 1925, F.A.H Schreinemakers derived and demonstrated the usefulness of a set of rules which is aptly suited to overcoming this problem. When some subset of the n+2 univariant lines that meet at an invariant point in an n-component system are known, this set of topologically-governed principles, which later came to be known as Schreinemakers rules, not only allows the determination of the location of remaining univariant lines, it also provides insights into the stability of divariant assemblages around the invariant point at various temperatures and pressures. In this paper, we review the 180° rule, overlap rule and half-plane rule, all of which make up Schreinemakers rules, and show how they can be applied to a ternary non-degenerate system where five phases coexist at an invariant point.